个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职:化学学院副院长
其他任职:辽宁省教学名师,宝钢优秀教师特等奖提名奖,中国分析测试学会青年学术委员会委员
性别:女
毕业院校:南京大学
学位:博士
所在单位:化学学院
学科:分析化学. 生物化学与分子生物学
办公地点:化工综合楼C305
电子邮箱:wushuo@dlut.edu.cn
Intramolecular RET Enhanced Visible Light-Absorbing Bodipy Organic Triplet Photosensitizers and Application in Photooxidation and Triplet-Triplet Annihilation Upconversion
点击次数:
论文类型:期刊论文
发表时间:2013-07-17
发表刊物:JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
收录刊物:SCIE、EI、PubMed、Scopus
卷号:135
期号:28
页面范围:10566-10578
ISSN号:0002-7863
摘要:Resonance energy transfer (RET) was used for the first time to enhance the visible light absorption of triplet photosensitizers. The intramolecular energy donor (boron-dipyrromethene, Bodipy) and acceptor (iodo-Bodipy) show different absorption bands in visible region, thus the visible absorption was enhanced as compared to the monochromophore triplet photosensitizers (e.g., iodo-Bodipy). Fluorescence quenching and excitation spectra indicate that the singlet energy transfer is efficient for the dyad triplet photosensitizers. Nanosecond time-resolved transient absorption spectroscopy has confirmed that the triplet excited states of the dyads are distributed on both the energy donor and acceptor, which is the result of forward singlet energy transfer from the energy donor to the energy acceptor and in turn the backward triplet energy transfer. This 'ping-pong' energy transfer was never reported for organic molecular arrays, and so it is useful to study the energy level of organic chromophores. The triplet photosensitizers were used for singlet oxygen (O-1(2)) mediated photooxidation of 1,5-dihydroxylnaphthalene to produce juglone. The visible light absorption of the new visible light-absorbing triplet photosensitizers are higher than the conventional monochromophore based triplet photosensitizers, as a result, the O-1(2) photosensitizing ability is improved with the new triplet photosensitizers. Triplet-triplet annihilation upconversion with these triplet photosensitizers was also studied. Our results are useful to design the triplet photosensitizers showing strong visible light absorbance and for their applications in photocatalysis and photodynamic therapy.