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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：男
毕业院校：兰州大学
学位：博士
所在单位：化工学院
学科：有机化学. 药物化学. 精细化工
办公地点：西部校区化工实验楼G-413
联系方式：0411-84986190 15942819406
电子邮箱：bmwang@dlut.edu.cn
Versatile Reactivity of CH3CN-Coordinated Nickel-Iron Heterodimetallic Complexes with Cp* Ligand on Diazadithiolate (N2S2) or Dithiadithiolate (S-4) Platforms
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论文类型：期刊论文
发表时间：2015-06-01
发表刊物：EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
收录刊物：SCIE、Scopus
卷号：2015
期号：18
页面范围：2965-2973
ISSN号：1434-1948
关键字：Nickel; Iron; S ligands; Bioinorganic chemistry; Enzyme models; Electrocatalysis
摘要：By using 3,7-dithianonane-1,9-dithiol (S-4) and N,N-dimethyl-N,N-bis(2-mercaptoethyl)ethylenediamine (N2S2) as ligands, two CH3CN-coordinated nickel-iron heterodimetallic complexes, [NiS4Fe(CH3CN)Cp*][PF6] (1a) and [NiN2S2Fe(CH3CN)Cp*][PF6] (1b) (Cp* = (5)-C5Me5), were synthesized and characterized spectroscopically and crystallographically. Reactivities of 1a and 1b towards CO, CH2Cl2, HBF4, and NOPF6 have also been investigated. A series of complexes coordinated with small molecules [NiS4Fe(L)Cp*][PF6](n) [n = 1, L = Cl (2a), CO (3a); n = 2, L = NO (4a)], [NiN2S2Fe(L)Cp*][PF6] [L = Cl (2b), CO (3b)] were obtained. We also studied the redox properties of 2a, 2b, 3a, and 3b by cyclic voltammetry in CH2Cl2 and in CH3CN solution. Complex 3a was found to be an excellent electrocatalyst for proton reduction from HBF4.