大连理工大学主页平台管理系统王保民--中文主页-- Numerical simulation to the effect of air in dam-break problem

论文成果

Highly Efficient and Regioselective Allylation with Allylic Alcohols Catalyzed by [Mo3S4Pd(eta(3)-allyl)] Clusters

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论文类型：期刊论文
发表时间：2010-06-18
发表刊物：ORGANIC LETTERS
收录刊物：SCIE、PubMed、Scopus
文献类型：J
卷号：12
期号：12
页面范围：2726-2729
ISSN号：1523-7060
摘要：A highly efficient and regioselective allylation reaction of amines and active methylene compounds directly using allylic alcohols under mild conditions catalyzed by the novel cubane-type sulfido [(Cp*Mo)(3)(mu(3)center dot S)(4)Pd(eta(3)-allyl)][PF6](2) clusters has been developed. A variety of allylic alcohols and nucleophiles including amines and active methylene compounds are investigated, and in the case of allylic alcohols bearing substituents at either the alpha- or gamma-position only linear products are obtained.

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