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论文类型：期刊论文

发表时间：2011-02-01

发表刊物：JOURNAL OF MATERIALS RESEARCH

收录刊物：Scopus、SCIE、EI

卷号：26

期号：3

页面范围：443-448

ISSN号：0884-2914

摘要：Nitrogen-doped multiwalled carbon nanotubes (N-doped MWNTs) were synthesized in a large quantity by the pyrolysis of pyridine at various temperatures in the range of 750-950 degrees C. The influence of temperature on the morphology, composition, thermal stability, and bonding nature of N-doped MWNTs was investigated. It is found that the yield of N-doped MWNTs increases linearly with the increase of the growth temperature. The maximum N content (4.6 at%) in MWNTs was obtained from a sample grown at 900 degrees C. N-doped MWNTs synthesized at 950 degrees C possess a unique drumlike morphology with the highest oxidizing temperature (535 degrees C). It is evidenced that N atoms are incorporated into the graphitic network in three different bonding forms and their relative content is affected by the growth temperature, which shows a clear influence on the morphology of N-doped MWNTs.