李斐

个人信息Personal Information

研究员

博士生导师

硕士生导师

性别:男

毕业院校:大连理工大学

学位:博士

所在单位:化工学院

学科:精细化工

办公地点:大连理工大学西部校区E-302

电子邮箱:lifei@dlut.edu.cn

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Efficient Electrocatalytic Water Oxidation by a Copper Oxide Thin Film in Borate Buffer

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论文类型:期刊论文

发表时间:2015-02-01

发表刊物:ACS CATALYSIS

收录刊物:SCIE、EI、Scopus、ESI高被引论文

卷号:5

期号:2

页面范围:627-630

ISSN号:2155-5435

关键字:water splitting; copper; electrocatalysis; water oxidation; thin film

摘要:A robust water oxidation catalyst based on copper oxide was prepared by facile electrodeposition of Cu2+ from borate buffer solution under near neutral conditions. The Cu-B-i thin film exhibits high activity and long-term stability in Cu2+-free pH 9 borate buffer. A steady current density of 1.2 mA/cm(2) was sustained for at least 10 h at 1.3 V versus NHE without iR compensation, which sets a new benchmark for copper-based OEC.