点击次数：

论文类型：期刊论文

发表时间：2014-06-01

发表刊物：CHEMISTRY-AN ASIAN JOURNAL

收录刊物：SCIE、EI、PubMed、Scopus

卷号：9

期号：6

页面范围：1515-1518

ISSN号：1861-4728

关键字：homogeneous catalysis; iron complex; oxygen evolution; renewable resources; water splitting

摘要：The activity of eleven separated iron complexes and nine in situ-generated iron complexes towards catalytic water oxidation have been examined in aqueous solutions with Ce(NH4)(2)(NO3)(6) as the oxidant. Two iron complexes bearing tridentate and tetradentate macrocyclic ligands were found to be novel water oxidation catalysts. The one with tetradentate ligand exhibited a promising activity with a turnover number of 65 for oxygen evolution.