李昱鹏

个人信息Personal Information

副教授

博士生导师

硕士生导师

性别:男

毕业院校:吉林大学

学位:博士

所在单位:材料科学与工程学院

学科:材料表面工程

电子邮箱:ypli@dlut.edu.cn

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Tunable wettability and pH-responsiveness of plasma copolymers of acrylic acid and octafluorocyclobutane

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论文类型:期刊论文

发表时间:2017-10-01

发表刊物:PLASMA PROCESSES AND POLYMERS

收录刊物:Scopus、SCIE、EI

卷号:14

期号:10

ISSN号:1612-8850

关键字:hydrophilic coatings; hydrophobic coatings; pH-responsiveness; plasma copolymers; surface modification; tunable wettability

摘要:Novel and intelligent plasma copolymers based on hydrophilic/hydrophobic monomers with tunable wettability and pH-responsiveness are demonstrated. A series of plasma copolymer coatings with various carboxylic acid and fluorocarbon group ratio are prepared on the low-density polyethylene (LDPE) surfaces via capacitively coupled radio frequency plasma (CCP). The static water contact angles (SWCA) of C4F8-co-AA plasma polymer coatings on nanotextured LDPE surfaces tuned from 163 to 4 degrees. These C4F8-co-AA plasma polymer coatings showed different pH-responsiveness by the combined effect of the carboxylic acid to fluorocarbon group ratios and surface nanotexture. The increase of carboxylic acid groups of C4F8-co-AA plasma polymers shifted the reversibly switchable wettability of pH-responsiveness towards low SWCA range. The magnifying effect of surface nanotexture on pH-responsiveness was also observed.