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Asymmetric Transfer Hydrogenation of 3-Nitroquinolines: Facile Access to Cyclic Nitro Compounds with Two Contiguous Stereocenters

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Indexed by:期刊论文

Date of Publication:2013-07-01

Journal:CHEMISTRY-AN ASIAN JOURNAL

Included Journals:SCIE、EI、Scopus

Volume:8

Issue:7

Page Number:1381-1385

ISSN No.:1861-4728

Key Words:asymmetric catalysis; organocatalysis; nitro compounds; transfer hydrogenation

Abstract:Hi, neighbor! The first organocatalyzed asymmetric transfer hydrogenation of aromatic nitro compounds was successfully developed with up to 99 % ee. The new methodology provides a direct and facile access to enantiopure cyclic nitro compounds with two contiguous stereocenters. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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