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个人信息Personal Information
教授
博士生导师
硕士生导师
性别：女
毕业院校：吉林大学理化所
学位：博士
所在单位：化学学院
电子邮箱：liyanqin@dlut.edu.cn
PdCl2 immobilized on metal-organic framework CuBTC with the aid of ionic liquids: enhanced catalytic performance in selective oxidation of cyclohexene
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论文类型：期刊论文
发表时间：2016-01-01
发表刊物：RSC ADVANCES
收录刊物：SCIE、EI
卷号：6
期号：39
页面范围：33048-33054
ISSN号：2046-2069
摘要：Metal-organic framework CuBTC was employed as a support to immobilize PdCl2 with the aid of ionic liquids (ILs). The as-synthesized PdCl2-ILs/CuBTC catalyst was studied in selective oxidation of cyclohexene with molecular oxygen as an oxidant and TBHP as an initiator. It is found that the allylic oxidation and radical oxidation processes are main reaction pathways. More importantly, the enhancement of catalytic activity in the oxidation of cyclohexene is observed over the PdCl2-IL/CuBTC catalyst due to Pd-Cu cooperative catalysis. Furthermore, ionic liquids could have a very favourable role in the stabilization of Pd(II) species and improvement of catalyst reusability.