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论文类型：期刊论文

发表时间：2015-07-01

发表刊物：SCIENCE BULLETIN

收录刊物：SCIE、CSCD、Scopus

卷号：60

期号：14

页面范围：1281-1286

ISSN号：2095-9273

关键字：Quantum-sized CdS; TiO2 nanotube array; Photoelectrochemical property

摘要：Quantum-sized CdS-coated TiO2 nanotube array (Q-CdS-TiO2 NTA) was fabricated by the modified successive ionic layer absorption and reaction method. Scanning electron microscope and transmission electron microscope images showed the regular structure of TiO2 NTA, where quantum-sized CdS (diameter <10 nm) deposited on both the inside and outside of TiO2 nanotube wall. Fabrication conditions including immersing cycles, calcination temperature and drying process were well optimized, and the Q-CdS-TiO2 NTA and its photoelectrochemical (PEC) properties were characterized by X-ray fluorescence spectrometer, UV-Vis diffuse reflectance spectra and photovoltage. Distinct increases in visible light absorption and photocurrent were observed as the immersing cycle was increased from 5 to 20 times. The additional drying process accelerated the CdS crystal growth rate, and thus, the fabrication time could be shortened accordingly. Calcination temperature influenced the PEC property of Q-CdS-TiO2 NTA deeply, and the optimized calcination temperature was found as 500 degrees C. As the Q-CdS-TiO2 NTA was fabricated under such condition, the visible photocurrent density increased to 2.8 mA/cm and the photovoltage between 350 and 480 nm was enhanced by 2.33 times than that without calcination. This study is expected to optimize Q-CdS-TiO2 NTA fabrication conditions for the purpose of improving its PEC performance.