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论文类型：期刊论文

发表时间：2013-02-01

发表刊物：APPLIED SURFACE SCIENCE

收录刊物：SCIE、EI

卷号：266

页面范围：344-349

ISSN号：0169-4332

关键字：Electron beam melting; Evaporation; Removal mechanism; Phosphorus; Silicon

摘要：An experimental investigation into the removal of phosphorus from molten silicon using electron beam melting has been carried out. The time variation of phosphorus content is obtained at the electron beam power of 9, 15, and 21 kW, respectively. The results show that, at a constant power, the content of phosphorus decreases rapidly within the range of approximately 0-900 s after silicon is melted completely, and then tends to level out with further extension of the melting time. The content of phosphorus is decreased from 33.2 x 10(-4) wt.% to 0.07 x 10(-4) wt.% after 1920 s at a power of 21 kW, which achieves the target for solar-grade silicon of less than 0.1 x 10(-4) wt.%. Moreover, the removal reaction of phosphorus by evaporation from the surface of silicon melt during electron beam melting occurs in accordance with the first order kinetics. The mass transfer coefficients in different removal steps are calculated and discussed, which indicate the removal reaction of phosphorus is controlled by both the transport of phosphorus atom from the bulk to the melt free surface and the vaporization from the free melt surface into the gas phase. (c) 2012 Elsevier B.V. All rights reserved.