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A Polymer Electrolyte Membrane Fuel Cell Based on Zirconium Phosphate and Phosphoric Acid

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Indexed by:期刊论文

Date of Publication:2009-01-01

Journal:ELECTROCHEMICAL AND SOLID STATE LETTERS

Included Journals:SCIE、EI、Scopus

Volume:12

Issue:12

Page Number:B171-B175

ISSN No.:1099-0062

Abstract:Poly(tetrafluoro ethylene) zirconium phosphate (PTFE/ZrP(2)O(7)center dot xHPO(3)) composite membranes were fabricated to develop a fuel cell membrane for operation at temperatures from 120 to 200 degrees C. A porous PTFE membrane was used as the membrane-supporting structure and ZrP(2)O(7)center dot xHPO(3) sol as the proton conductor. The PTFE/ZrP(2)O(7)center dot xHPO(3) membrane had a high proton conductivity greater than 0.1 S cm(-1) at 0% relative humidity. The mechanical strength of the composite membrane was good, exhibiting a load before a rupture of 10.25 MPa. The PTFE/ZrP(2)O(7)center dot xHPO(3) composite membrane is a promising material for the intermediate temperature proton-conducting membrane fuel cell. (C) 2009 The Electrochemical Society. [DOI:10.1149/1.3242214] All rights reserved.

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