Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2011-02-09

Journal: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Included Journals: PubMed、EI、SCIE、Scopus

Volume: 133

Issue: 5

Page Number: 1147-1149

ISSN: 0002-7863

Abstract: A series of well-defined thiolate-bridged diiron clusters bearing the cis-HN = NH ligand, [Cp(+)Fe(mu-SEt)(2)-(mu-eta(1):eta(1)-HN = NH)FeCp(+)][PF(6)] (Cp(+) = eta(5)-C(5)Me(4)H or eta(5)-C(5)Me(5)), are successfully prepared in high yields and fully characterized by spectroscopy and X-ray crystallography. Under moderate conditions, these new Fe/S clusters exhibit high activity, not only for the catalytic cleavage of the N-N bond of hydrazines but also for the activation and coupling of terminal alkynes.