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Indexed by:期刊论文

Date of Publication:2011-02-09

Journal:JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Included Journals:Scopus、SCIE、EI、PubMed

Volume:133

Issue:5

Page Number:1147-1149

ISSN No.:0002-7863

Abstract:A series of well-defined thiolate-bridged diiron clusters bearing the cis-HN = NH ligand, [Cp(+)Fe(mu-SEt)(2)-(mu-eta(1):eta(1)-HN = NH)FeCp(+)][PF(6)] (Cp(+) = eta(5)-C(5)Me(4)H or eta(5)-C(5)Me(5)), are successfully prepared in high yields and fully characterized by spectroscopy and X-ray crystallography. Under moderate conditions, these new Fe/S clusters exhibit high activity, not only for the catalytic cleavage of the N-N bond of hydrazines but also for the activation and coupling of terminal alkynes.