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Indexed by:期刊论文

Date of Publication:2010-06-28

Journal:DALTON TRANSACTIONS

Included Journals:SCIE、EI、PubMed

Volume:39

Issue:24

Page Number:5658-5663

ISSN No.:1477-9226

Abstract:The heterometallic cubane-type clusters [(Cp* Mo)(3)(mu(3)-S)(4)Au(PR3)][PF6][X] (Cp* = eta(5)-Me-C5(5); 2a: R = Ph, X = BF4; 2b: R = Cy, X = PF6; 2c: R = 'Bu, X = PF6), [(Cp*Mo)(3)(mu(3)-S)(4)Ag(PPh3)][PF6][OTf] (3, OTf = OSO2CF3) and [(Cp* Mo)(3)(mu(3)-S)(4)CuI][PF6] (4) have been prepared by the reaction of [(Cp*Mo)(3)(mu(2)-S)(3)(mu(3)-S)][PF6] (1) with complexes [(R3P) Au][X], [(Ph3P) Ag][OTf] and CuI, respectively. These clusters have been spectroscopically and crystallographically characterized. In addition, the electrochemical properties of clusters 2a, 2b, 2c and 4 are also discussed.