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Mechanism for acetone sensing property of Pd-loaded SnO2 nanofibers prepared by electrospinning: Fermi-level effects

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2015-03-01

Journal: JOURNAL OF MATERIALS SCIENCE

Included Journals: Scopus、EI、SCIE

Volume: 50

Issue: 6

Page Number: 2605-2615

ISSN: 0022-2461

Abstract: Undoped and Pd-loaded SnO2 nanofibers with various Pd loading concentrations from 1.0 to 2.0 mol% had been synthesized by electrospinning with appropriate annealing process subsequently. The morphologies and nanocrystalline structures of the nanofibers were characterized by thermogravimetric analysis-differential scanning calorimetry, X-ray diffraction, Fourier transform infrared, energy dispersive X-ray spectroscopy, scanning electron microscopy, transmission electron microscopy, and N-2 physical adsorption. The sensing properties of undoped and Pd-loaded SnO2 nanofibers were compared. The gas sensing results showed that 1.5 mol% Pd-loaded SnO2 nanofibers got a best response to acetone at lower operating temperature of 275 A degrees C among all the Pd-loaded SnO2 nanofibers. The enhanced acetone response of Pd-loaded SnO2 nanofibers may be correlated with the "Fermi-level effects" of Pd catalysts.

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