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Preparation of modified MWCNTs-doped PANI nanorods by oxygen plasma and their ammonia-sensing properties

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Indexed by:期刊论文

Date of Publication:2013-05-01

Journal:JOURNAL OF MATERIALS SCIENCE

Included Journals:SCIE、EI

Volume:48

Issue:9

Page Number:3597-3604

ISSN No.:0022-2461

Abstract:Multi-wall carbon nanotubes (MWCNTs)-doped polyaniline (PANI) nanopowders were prepared by chemical oxidation polymerization. Then, the MWCNTs-doped PANI nanopowders were modified by a radio frequency (RF) oxygen plasma source. The morphology and structure of modified MWCNTs-doped PANI nanorods were analyzed by SEM and FI-IR. Gas sensors were fabricated based on plasma modified MWCNTs-doped PANI nanorods to detect ammonia at room temperature. The response amplitude of the gas sensor based on modified MWCNTs-doped PANI nanorods was much higher than those of MWCNTs-doped PANI nanopowders and pure PANI nanopowders sensors, respectively, in ammonia concentration range of 10-150 ppm. Cross responses of modified MWCNTs-doped PANI nanorods sensor to ammonia, ethanol, formaldehyde, and toluene were tested. The sensor showed good selectivity and stability. The sensing mechanism of modified MWCNTs-doped PANI nanorods gas sensor was analyzed.

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