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Rhodium-Catalyzed Oxidative Benzannulation of N-Adamantyl-1-naphthylamines with Internal Alkynes via Dual C-H Bond Activation: Synthesis of Substituted Anthracenes

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Indexed by:期刊论文

Date of Publication:2016-09-02

Journal:ORGANIC LETTERS

Included Journals:SCIE、PubMed、Scopus

Volume:18

Issue:17

Page Number:4246-4249

ISSN No.:1523-7060

Abstract:Rhodium-catalyzed oxidative benzannulation of N-adaffianty1-1-naphthylarnines with internal alkynes to produce highly substituted anthracenes in satisfactory to good yields was developed. The annulation reaction proceeded smoothly under mild conditions in the presence of [Cp*RhCl2](2) as the precatalyst and Cu(OAc)(2) as the oxidant.

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