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论文类型： 期刊论文

发表时间： 2016-09-01

发表刊物： JOURNAL OF ENERGY CHEMISTRY

收录刊物： SCIE、EI、ISTIC、CSCD、Scopus

卷号： 25

期号： 5

页面范围： 769-774

ISSN号： 2095-4956

关键字： Dye-sensitized solar cells; Organic dye; Bis-triphenylamine; Electron donor; Photon-to-current conversion efficiency

摘要： New metal-free organic dye sensitizers containing mono-triphenylamine or bis-triphenylamine as the electron donor, a thiophene as the pi-conjugated system, and a cyanoacrylic acid moiety as the electron acceptor were synthesized. The optical and electrochemical properties of the dyes were investigated, and their performance as sensitizers in solar cells was evaluated. Dye-sensitized solar cells based on dye containing bis-triphenylamine as the electron donor produced a photon-to-current conversion efficiency of 6.06% (Jsc = 14.21 mA/cm(2), Voc = 0.62 V, ff = 0.69) under 100 mW/cm(2) simulated AM 1.5 G solar irradiation (100 mW/cm(2)). (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.