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个人信息Personal Information
教授
博士生导师
硕士生导师
任职 : 精细化工国家重点实验室，副主任
性别：男
毕业院校：大连理工大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区化工实验楼F-212A
联系方式：0411-84986249
电子邮箱：dr.gaoyan@dlut.edu.cn
Artificial photosynthesis: photosensitizer/catalyst supramolecular assemblies for light driven water oxidation.
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论文类型：期刊论文
发表时间：2014-07-01
发表刊物：Faraday discussions
收录刊物：PubMed
卷号：176
页面范围：225-32
ISSN号：1359-6640
摘要：Three new supramolecular assemblies SA1-SA3 with different linkages between the photosensitizer and catalyst have been synthesized for light driven water oxidation. With flexible -CH(2)-CH(2)- chains as the linkage, the assembly SA3 displays the best performance for photocatalytic water oxidation compared with the other two assemblies, a turnover number of 34 has been obtained based on the molecular assembly SA3 in a homogeneous system. This type of assembly connected with flexible linkages represents suitable candidates to construct photoanodes for light driven water splitting in dye sensitized photoelectrochemical devices.