A dual shell-like heptadecanuclearity [Gd5Ni12] cluster with ferromagnetic interaction and large magnetocaloric effect
Release Time:2019-03-09 Hits:
Indexed by: Journal Article
Date of Publication: 2013-04-01
Journal: INORGANIC CHEMISTRY COMMUNICATIONS
Included Journals: SCIE
Volume: 30
Page Number: 58-61
ISSN: 1387-7003
Key Words: Heptadecanuclearity; Dual shell; Coligand; Ferromagnetic interaction; Magnetocaloric effect
Abstract: A new dual shell-like heptadecanuclearity [Gd5Ni12(Pro)(9)(CMP)(6)(mu(3)-OH)(9)(mu(2)-OH)(3)(H2O)(3)]center dot Cl-6 center dot 23H(2)O (1) cluster with proline (HPro) and N-carboxymethyl-L-proline (H2CMP) as coligands has been successfully synthesized and characterized. The compound consists of rare trigonal bipyramid {Gd-5} core and triangular orthobicupola {Ni-12} outer shell. The magnetic studies reveal that 1 shows ferromagnetic interactions and a large magnetocaloric effect (22.4 J kg(-1) K-1, Delta H = 7 T). (C) 2013 Elsevier B.V. All rights reserved.
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