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    张建军

    • 教授     博士生导师   硕士生导师
    • 性别:男
    • 毕业院校:南京大学
    • 学位:博士
    • 所在单位:化学学院
    • 学科:无机化学
    • 办公地点:化工综合楼D411
    • 联系方式:0411-84986036
    • 电子邮箱:zhangjj@dlut.edu.cn

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    Two one-dimensional compounds based on pyramidal {TbCu4} units and formate ligand: chair-like [(H2O)(2)(ClO4)(2)](2-) clusters and slow relaxation of magnetization

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    论文类型:期刊论文

    发表时间:2012-11-21

    发表刊物:DALTON TRANSACTIONS

    收录刊物:SCIE、EI、PubMed、Scopus

    卷号:41

    期号:43

    页面范围:13264-13266

    ISSN号:1477-9226

    摘要:With formate as ligand, two 1-D 3d-4f compounds (linear and zigzag) based on pyramidal {TbCu4} unit were obtained. Chair-like [( H2O)(2)(ClO4)(2)](2-) clusters and mu(5)-eta(1):eta(4) bridging mode of formate were observed in the linear one which also displays slow relaxation of the magnetization.