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Indexed by:期刊论文

Date of Publication:2012-07-01

Journal:CHINESE CHEMICAL LETTERS

Included Journals:SCIE、ISTIC

Volume:23

Issue:7

Page Number:773-776

ISSN No.:1001-8417

Key Words:Pd/C catalyst; alpha,beta-Unsaturated aldehydes; Hydrogenation; Selectivity

Abstract:Selective hydrogenation of alpha,beta-unsaturated aldehydes with modified Pd/C catalyst was developed. The reduction of C=O bond could be efficiently inhibited by the addition of carbonates, and high selectivity to the corresponding saturated aldehydes was achieved under mild conditions. This protocol provides an alternative for efficient preparation of saturated aldehydes. (C) 2012 Ze Ming Rong. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.