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Selective Hydrogenation of Single Benzene Ring in Biphenyl Catalyzed by Skeletal Ni

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Indexed by:期刊论文

Date of Publication:2009-11-01

Journal:CHEMCATCHEM

Included Journals:SCIE、EI、Scopus

Volume:1

Issue:3

Page Number:369-371

ISSN No.:1867-3880

Key Words:chemoselectivity; heterogeneous catalysis; hydrogenation; nickel; reduction

Abstract:The nickel lining on a Raney day: Highly selective catalytic hydrogenation of biphenyl (BP) to cyclohexylbenzene (CHB) was achieved by using skeletal Ni prepared from rapidly quenched Ni-Al alloys ribbons, affording 100% conversion and 99.4% selectivity in a one-pot reaction. © 2009 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.

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