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Selective Hydrogenation of Single Benzene Ring in Biphenyl Catalyzed by Skeletal Ni

Release Time:2019-03-09  Hits:

Indexed by: Journal Article

Date of Publication: 2009-11-01

Journal: CHEMCATCHEM

Included Journals: Scopus、EI、SCIE

Volume: 1

Issue: 3

Page Number: 369-371

ISSN: 1867-3880

Key Words: chemoselectivity; heterogeneous catalysis; hydrogenation; nickel; reduction

Abstract: The nickel lining on a Raney day: Highly selective catalytic hydrogenation of biphenyl (BP) to cyclohexylbenzene (CHB) was achieved by using skeletal Ni prepared from rapidly quenched Ni-Al alloys ribbons, affording 100% conversion and 99.4% selectivity in a one-pot reaction. © 2009 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.

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