个人信息Personal Information
教授
博士生导师
硕士生导师
性别:男
毕业院校:中科院大连化学物理研究所
学位:博士
所在单位:化工学院
学科:工业催化. 能源化工
办公地点:西部校区化工实验楼B-323
联系方式:0411-84986326
电子邮箱:wpzhang@dlut.edu.cn
Cu-exchanged Al-rich SSZ-13 zeolite from organotemplate-free synthesis as NH3-SCR catalyst: Effects of Na+ ions on the activity and hydrothermal stability
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论文类型:期刊论文
发表时间:2017-11-15
发表刊物:APPLIED CATALYSIS B-ENVIRONMENTAL
收录刊物:SCIE、EI
卷号:217
页面范围:421-428
ISSN号:0926-3373
关键字:NH3-SCR; Cu-SSZ-13 catalyst; Organotemplate-free synthesis of SSZ-13; Na+ effect; Hydrothermal stability
摘要:The relatively low activity at lower temperatures and high cost of SSZ-13 zeolite from organotemplate synthesis are two of major problems of presently commercialized Cu-SSZ-13 catalysts for NH3-SCR reaction. Cu-exchanged Al-rich SSZ-13 catalysts with Si/Al=4 from organotemplate-free synthesis have been prepared, and show superior NH3-SCR performance with NO conversions above 85% at wide-temperature window ranging from 150 to 650 degrees C. Cu-Na-SSZ-13 catalysts with varied amount of residual Na+ were prepared by partial ion-exchange of as-prepared Al-rich Na-SSZ-13, and it's found that Cu-Na-SSZ-13 catalyst with moderate Na+ content can improve both the low-temperature activity and its hydrothermal stability. Al-27 and H-1 MAS NMR spectra indicate that residual Na+ can stabilize the framework Al in Al-rich SSZ-13 zeolite. UV-Vis-NIR and H-2-TPR spectra demonstrate that Na+ co-cations enhance the reducibility of Cu2+, whereas too much amount of Na+ may result in the formation of CuOx, during the hydrothermal treatment, and further decrease the hydrothermal stability of Cu-Na-SSZ-13 catalyst. The optimized organotemplate-free Cu-Na-SSZ-13 with 2.7 wt% Cu and 1.7 wt% Na exhibits almost the same NO conversions as the commercial high-silica Cu-SSZ-13 catalyst at 150-550 degrees C after 750 and 800 degrees C hydrothermal aging, and shows promising practical applications. (C) 2017 Elsevier B.V. All rights reserved.