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论文类型：期刊论文

发表时间：2012-01-21

发表刊物：DALTON TRANSACTIONS

收录刊物：SCIE、EI、Scopus

卷号：41

期号：3

页面范围：990-994

ISSN号：1477-9226

摘要：The synthesis process of aluminophosphate AlPO4-11 molecular sieve in the mixed water/1-butyl-3-methylimidazolium bromide ([bmim]Br) ionic liquid was investigated by XRD, multinuclear solid-state NMR, scanning electron microscopy (SEM) and X-ray energy dispersive spectroscopy (EDS). It was observed that a tablet phase, named SIZ-2, was formed at the early stage of crystallization. During crystallization metastable SIZ-2 with an incompletely condensed framework phosphorus disappeared gradually, and the phosphorous species became fully condensed through hydroxyl reaction with tetrahedral aluminum to form thermodynamically stable AlPO4-11 in the final product. It was found that [bmim] Br, acting as the structure-directing agent, was occluded into the AlPO4-11 channel.