期刊论文

Liu, Yanming

Quan, X (reprint author), Dalian Univ Technol, Fac Chem Environm & Biol Sci & Technol, Key Lab Ind Ecol & Environm Engn, Minist Educ, Dalian 116024, Peoples R China.

Yu, Hongtao,Hoffmann, Michael R.,Zhang, Yujing,Cheng, Kai,Quan, Xie,Fan, Xinfei,Su, Yan,Chen, Shuo,Zhao, Huimin,Zhang, Yaobin

2017-12-04

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SCIE、EI、PubMed、Scopus

J

56

49

15607-15611

1433-7851

CO2 reduction; doped nanodiamond; electrocatalysis; ethanol; heterogeneous catalysis

Electrochemical reduction of CO2 to ethanol, a clean and renewable liquid fuel with high heating value, is an attractive strategy for global warming mitigation and resource utilization. However, converting CO2 to ethanol remains great challenge due to the low activity, poor product selectivity and stability of electrocatalysts. Here, the B- and N-co-doped nanodiamond (BND) was reported as an efficient and stable electrode for selective reduction of CO2 to ethanol. Good ethanol selectivity was achieved on the BND with high Faradaic efficiency of 93.2% (-1.0V vs. RHE), which overcame the limitation of low selectivity for multicarbon or high heating value fuels. Its superior performance was mainly originated from the synergistic effect of B and N co-doping, high N content and overpotential for hydrogen evolution. The possible pathway for CO2 reduction revealed by DFT computation was CO2 ->*COOH ->*CO ->*COCO ->*COCH2OH ->*CH2OCH2OH -> CH3CH2OH.