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发布时间：2019-03-09

论文类型：期刊论文

发表时间：2014-12-21

发表刊物：NANOSCALE

收录刊物：Scopus、PubMed、SCIE

卷号：6

期号：24

页面范围：14617-14621

ISSN号：2040-3364

摘要：Our studies show that VSi12- adopts a V-centered hexagonal prism with a singlet spin state. The addition of the second V atom leads to a capped hexagonal antiprism for V2Si12- in a doublet spin state. Most interestingly, V3Si12- exhibits a ferrimagnetic, bicapped hexagonal antiprism wheel-like structure with a total spin of 4 mu(B).