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论文类型：期刊论文

发表时间：2015-02-21

发表刊物：DALTON TRANSACTIONS

收录刊物：SCIE、EI、PubMed、Scopus

卷号：44

期号：7

页面范围：3393-3398

ISSN号：1477-9226

摘要：One trinuclear and two tetranuclear cyanide-bridged Fe-III-Ni-II complexes were synthesized via treatment of a tricyanometallate with divalent Ni salts in the presence of 1-butylimidazole, 2,2-bipyrimidyl and 1,10-phenanthroline, respectively. Magnetic property studies demonstrated that the three complexes exhibit single-molecule magnet behavior as a result of strong intracluster ferromagnetic coupling and weak intercluster magnetic interactions.