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Indexed by:期刊论文

Date of Publication:2016-11-01

Journal:NANOMATERIALS

Included Journals:SCIE、PubMed、Scopus

Volume:6

Issue:11

ISSN No.:2079-4991

Key Words:graphene nanoplatelets (GNPs); cement paste; mechanical properties; porosity; morphology

Abstract:In this work, graphene nanoplatelets (GNPs) were dispersed uniformly in aqueous solution using methylcellulose (MC) as a dispersing agent via ultrasonic processing. Homogenous GNP suspensions were incorporated into the cement matrix to investigate the effect of GNPs on the mechanical behavior of cement paste. The optimum concentration ratio of GNPs to MC was confirmed as 1:7 by ultraviolet visible spectroscopy (UV-Vis), and the optical microscope and transmission electron microscopy (TEM) images displayed remarkable dispersing performance. The GNP-cement composite exhibited better mechanical properties with the help of surface-modified GNPs. The flexural strength of cement paste increased up to 15%-24% with 0.05 wt % GNPs (by weight of cement). Meanwhile, the compressive strength of the GNP-cement composite increased up to 3%-8%. The X-ray diffraction (XRD) and thermal analysis (TG/DTG) demonstrated that the GNPs could accelerate the degree of hydration and increase the amount of hydration products, especially at an early age. Meanwhile, the lower porosity and finer pore size distribution of GNP-cement composite were detected by mercury intrusion porosimetry (MIP). In addition, scanning electron microscope (SEM) analysis showed the introduction of GNPs could impede the development of cracks and preserve the completeness of the matrix through the plicate morphology and tortuous behavior of GNPs.