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论文类型：期刊论文

发表时间：2017-10-01

发表刊物：NANO ENERGY

收录刊物：Scopus、SCIE、EI

卷号：40

页面范围：336-344

ISSN号：2211-2855

关键字：Tin dioxide; Low temperature; Nanocrystals; UV resistance; Electron transfer layer; Perovskite solar cells

摘要：In fabrication of SnO2 electron transfer layer (ETL) via traditional solution routes, the strong dependence of film crystallization on high temperature annealing or robust thermal treatment makes it challengeable to prepare crystallized SnO2 ETLs at low temperature (< 150 degrees C). Here, we put forward a sol-gel route by which the whole fabrication process of crystallized SnO2 ETL below 80 degrees C is realized for the first time. In the new route, participation of atmosphere O-2 and H2O by refluxing is crucial as it can greatly promote Sn2+ oxidation and controlled hydrolysis in SnCl2 center dot 2H(2)O alcohol solution, in turn opening up an energetically favorable pathway for SnO2 crystallization at low temperature. Systematical investigations reveal that SnO2 ETLs have high conductivity and transmittance and appropriate energy band level, by which PSCs obtain superior photovoltaic performance, with a champion power conversion efficiency (PCE) and steady-state PCE of 19.20% and 18.48% achieved, respectively, much higher than that of the devices using high temperature annealed TiO2 ETLs (16.61% and 15.03%). The SnO2-ETL-based flexible PSCs also attain a high PCE up to 16.11% and among the highest records of flexible PSCs. Due to a larger band gap, SnO2-ETLs-based PSCs show superior UV resistance against high intensity UV light irradiation.