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Synthesis and characterization of star-comb styrene/butadiene copolymer

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Indexed by:期刊论文

Date of Publication:2010-11-01

Journal:CHINESE CHEMICAL LETTERS

Included Journals:SCIE、ISTIC、CSCD、Scopus

Volume:21

Issue:11

Page Number:1370-1373

ISSN No.:1001-8417

Key Words:Anionic polymerization; Epoxidation; Grafting reaction; Star-comb copolymer; Side chain

Abstract:A novel star-comb styrene/butadiene copolymer (SC-SBC) was synthesized by anionic polymerization and grafting reaction with epoxidized star liquid polybutadiene (ESPB) as coupling agent. The overall shape of the star-comb macromolecules can be altered by changing the molecular weight and number of the side chain. The molecular parameters and mechanical properties of the SC-SBC resins were investigated. The notched izod impact strength of the SC-SBC resins are excellent and reach as high as to 239 J/m. (C) 2010 Yang Li. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

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