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论文类型：期刊论文

发表时间：2016-03-15

发表刊物：JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

收录刊物：SCIE、EI、Scopus

卷号：54

期号：6

页面范围：735-739

ISSN号：0887-624X

关键字：functionalized; perylene bisimide; polystyrene; syndiotactic; synthesis

摘要：Si-H-containing syndiotactic polystyrene is synthesized by the direct polymerization of 4-vinyiphenyldimethylsilanol in the presence of a half-sandwich scandium catalyst system [(C5Me4SiMe3)Sc(CH2C6H4NMe2-o)2]/[Ph3C][B(C6F5)4]. By the one-step efficient hydrosilylation reaction, the perylene bisimide units are quantitatively linked to the Si-H-containing syndiotactic polystyrene backbone. The perylene bisimide units functionalized syndiotactic polystyrene exhibits liquid crystallinity, fluorescence, and electron transporting properties. ? 2015 Wiley Periodicals, Inc.