接金川

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博士生导师

硕士生导师

性别:男

毕业院校:哈尔滨工业大学

学位:博士

所在单位:材料科学与工程学院

学科:材料加工工程

办公地点:铸造中心101

联系方式:0411-84706220

电子邮箱:jiejc@dlut.edu.cn

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Influence of carbon vacancies on the adsorption of Au on TiC(001): a first-principles study

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论文类型:期刊论文

发表时间:2016-03-01

发表刊物:JOURNAL OF MATERIALS SCIENCE

收录刊物:SCIE、EI

卷号:51

期号:6

页面范围:2902-2910

ISSN号:0022-2461

摘要:In this work, it is found that the adsorption sites and geometries of Au clusters on TiC(001) surfaces containing carbon vacancies are significantly different from that without vacancies. In TiC(001) with carbon vacancies, the most preferential adsorption sites for Au are on top of vacancies sites, and then the sites neighboring the vacancies. The tendency for 3D Au clusters formation in TiC(001) with carbon vacancies is weaker and Au atoms are more likely to form rough 2D clusters. Furthermore, more charge is transferred from the substrate to Au and the polarization of electrons is stronger. In addition, the diffusion of Au on TiC(001) surface containing carbon vacancies is more difficult. The above affects can be helpful for improving the chemical activation of Au/TiC surfaces. Therefore, introducing carbon vacancies in the surfaces should be a very promising method to enhance the activation of Au/TiC systems.