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Indexed by:期刊论文

Date of Publication:2014-09-01

Journal:ACS MACRO LETTERS

Included Journals:SCIE、Scopus

Volume:3

Issue:9

Page Number:896-899

ISSN No.:2161-1653

Abstract:Lewis pair cooperation provides a facile approach for polymerizing dissymmetric divinyl polar monomers such as 4-vinylbenzyl methacrylate in excellent regioselectivity and high reactivity at mild conditions, affording soluble polymers bearing pendant active vinyl groups with high molecular weight (up to 6.4 x 10(5) g/mol) and narrow polydispersity (PDI < 1.5). ESI-TOF MS study demonstrated that the polymerization process only concerned the methacrylic double bond and selectively remained the pendant allylic or styrene C=C bond.