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杜健军
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教授   博士生导师   硕士生导师

性别: 男

毕业院校: 大连理工大学

学位: 博士

所在单位: 化工学院

学科: 精细化工

办公地点: 大连理工大学西部校区E-226

联系方式: 0411-84986304

电子邮箱: dujj@dlut.edu.cn

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Gold nanoparticle-based colorimetric detection of mercury ion via coordination chemistry

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论文类型: 期刊论文

发表时间: 2015-06-01

发表刊物: SENSORS AND ACTUATORS B-CHEMICAL

收录刊物: SCIE、EI

卷号: 212

页面范围: 481-486

ISSN号: 0925-4005

关键字: Colorimetric assay; Gold nanoparticle; Coordination chemistry; Thymine derivative; Mercury ion

摘要: A simple, fast, and convenient colorimetric detection of Hg2+ in aqueous media was presented based on the selective binding capability of thymine derivative (N-T) toward Hg2+. N-T decorated AuNPs solution was stable in red color, while the presence of Hg2+ induces significant aggregation of AuNPs along with red-to-blue color changes. Therefore, Hg2+ content in real water samples can be qualitatively detected by our naked eyes; meanwhile, good linear relationship of Hg2+ along with A(650 nm/520 nm) values could be obtained for its quantitative determination. Furthermore, our system shows excellent selectivity to mercury ions against any other tested metal ions and anions, and good sensitivity with LOD of 0.8 nM in real water samples. (C) 2015 Elsevier B.V. All rights reserved.

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