张晓鹏

Associate Professor   Supervisor of Master's Candidates

Gender:Male

Alma Mater:南开大学

Degree:Doctoral Degree

School/Department:化工海洋与生命学院

Discipline:Chemical Engineering. Industrial Catalysis

E-Mail:xiaopengzhang@dlut.edu.cn


Paper Publications

Cobalt modification for improving alkali metals resistance of Mn/Ce-ZrO2 in low-temperature selective catalytic reduction

Hits:

Date of Publication:2022-10-05

Journal:The 8th Global Chinese Chemical Engineers Symposium

Pre One:Co3O4-based catalysts derived from natural wood with hierarchical structure for elemental mercury oxidation

Next One:Cobalt modification for improving K resistance of Mn/Ce-ZrO2 in selective catalytic reduction

Profile

张晓鹏,1983年生,副教授,硕士生导师。

2013年获得南开大学工学博士学位,同年进入大连理工大学任教,2017年12月晋升副教授。发表SCI论文40余篇,参编专著及教材2部,授权专利5项,主持国家自然科学基金面上项目、国家自然科学基金青年项目,辽宁省联合基金等课题8项。

研究领域:先进催化材料、多相催化反应动力学及机理。通过催化剂精准合成,调控其表面形貌及电子态,增加表面活性位点同时降低传质阻力,实现反应物快速活化和污染物的高效脱除

具体研究方向:

  1. 环境催化:环境污染物NOx,Hg,CO等催化脱除

  2. 电催化:燃料电池阴极氧还原、电解水制氢

主持课题:

1.         Co3O4表面氧空位可控调变及其催化氧化燃煤烟气中单质汞的研究,国家自然科学基金面上项目

2.         低温SCR催化剂Mn/Co-Ce-Zr协同脱除含硫烟气中单质汞的基础研究,国家自然科学基金青年基金

3.         植物导管内嵌Co3O4纳米粒子催化剂制备及脱汞性能研究,辽宁省联合基金

4.         Co3O4催化剂晶面效应对燃煤烟气单质汞脱除效率的影响机制研究,交叉探索科研专题

5.         协同脱除催化裂化再生烟气中CONOx的高效催化剂研制,精细化工国家重点实验室专项项目

6.         低温SCR催化剂Mn/Al2O3对燃煤烟气中单质汞的脱除研究,基本科研业务费专项项目

7.         过渡金属掺杂改性有序介孔材料MCM-41的制备及其催化脱除燃煤烟气中单质汞的基础研究,基本科研业务费专项项目

8.         多功能化膜材料及催化材料的分子设计及性能研究,基本科研业务费专项项目

参与课题:

1.        有机非多孔膜的全过程研究,辽宁省“兴辽英才”计划项目杰出人才项目

2.         新型高效过程耦合强化创新团队,科技部创新人才推进计划-重点领域创新团队3.       低氢富CO2含杂石化尾气双膜-电化学氢泵原位分离常压加氢资源化,自然科学基金重点项目


发表文章:

[1]      Longzhu Li, Miao Yu, Cheng Gao, Xiaoming Yan, Ning Zhang, Junjiang Bao, Xiaopeng Zhang*. MoS2/CoS2 with heterostructure in-situ grown on the surface of electrospinning carbon nanotube for efficient hydrogen evolution reaction, Journal of Alloys and Compounds, 2024, 1003, 175530

[2]      Xiaopeng Zhang*, Cheng Gao , Longzhu Li , Xiaoming Yan , Ning Zhang , Junjiang Bao*. Fe based MOF encapsulating triethylenediamine cobalt complex to prepare a FeN3-CoN3 dual-atom catalyst for efficient ORR in Zn-air batteries, Journal of Colloid and Interface Science, 2024, 676, 871–883

[3]      Xiaopeng Zhang*, Hongda Zhu, Yuying Wei, Longzhu Li, Lianhao Zhang, Junjiang Bao, Ning Zhang. Oxygen vacancies tuning over Co3O4 nanosheet preferentially growing (220) facet for efficient Hg0 removal from flue gas, Fuel, 2024, 361, 130675

[4]      Xiaopeng Zhang, Lianhao Zhang, Longzhu Li, Cheng Gao, Ning Zhang, Junjiang Bao, Gaohong He*. Cobalt sulfide nanosheets synthesized by anion exchange method for efficient Hg0 removal from flue gas, Separation and Purification Technology, 2024, 330, 125314

[5]      Cheng Gao, Longzhu, Li, Xiaoming Yan, Ning Zhang, Junjiang Bao, Xiaopeng Zhang*, Yanqiang Li*. Triethylenediamine cobalt complex encapsulated in MOFs cage to prepare cobalt single atom catalyst with high Co-N4 density for efficient oxygen reduction reaction. Journal of Colloid and Interface Science, 2024, 653, 296-307

[6]      Xiaopeng Zhang, Yuying Wei, Lianhao Zhang, Xinxin Wang, Ning Zhang, Junjiang Bao, Gaohong He*. Co3O4 nanotubes embedded in the interlayer of GO nanosheets for efficient Hg0 removal from coal flue gas. Separation and Purification Technology, 2023, 320, 124014.

[7]      Xiaopeng Zhang, Yuying Wei, Lianhao Zhang, Xinxin Wang, Ning Zhang, Junjiang Bao, Gaohong He*. Self-template synthesis of CuCo2O4 nanosheet-based nanotube sorbent for efficient Hg0 removal. Separation and Purification Technology, 2023, 313, 123432.

[8]      Xinxin Wang, Xiaopeng Zhang*, Longzhu Li, Lianhao Zhang, Junjiang Bao, Ning Zhang. Using the composite material of GO and g-C3N4 nanosheets as substrate to in-situ grow Co3O4 nanosheets for efficient Hg0 removal. Fuel, 2023, 340, 127413

[9]      Xiaopeng Zhang, Xiangkai Han, Cheng Gao, Xinxin Wang, Yuying Wei, Ning Zhang, Junjiang Bao, Gaohong He*. In-situ growth of Co/Zn bimetallic MOF on GO surface to prepare GO supporting Co@C single-atom catalyst for Hg0 oxidation. Fuel, 2023, 333, 126135

[10]  Xiaopeng Zhang, Cheng Gao, Ziwei Wang, Ximiao Wang, Jie Cheng, Xinxin Song, Xiangkai Han, Ning Zhang, Junjiang Bao, Gaohong He*. Co3O4 with ordered pore structure derived from wood vessels for efficient Hg0 oxidation. Chinese Journal of Chemical Engineering, 2022, 50, 215-221

[11]  Xinxin Wang, Xiaopeng Zhang*, Yuying Wei, Cheng Gao, Junjiang Bao, Ning Zhang. In situ grown Co3O4 nanosheets in the interlayer space of g-C3N4 for efficient removal of Hg0 from flue gas. Fuel. 2022, 324, 124660.

[12]  Yuying Wei, Xiaopeng Zhang*, Cheng Gao, Xinxin Wang, Ning Zhang, Junjiang Bao, Gaohong He*. Self-template synthesis of Co3O4 nanotube for efficient Hg0 removal from flue gas. Separation and Purification Technology. 2022, 295, 121240.

[13]  Xiaopeng Zhang, Xiangkai Han, Yuying Wei, Xinxin Wang, Ning Zhang, Junjiang Bao, Gaohong He*. Single-atom Co-N-C catalyst for efficient Hg0 oxidation at low temperature. Chemical Engineering Journal. 2022, 428, 132660.

[14]  Xiaopeng Zhang, Xinxin Song, Xinxin Wang, Yuying Wei, Xiangkai Han, Junjiang Bao, Ning Zhang, Gaohong He*. In-situ grown Co3O4 nanoparticles on wood-derived carbon with natural ordered pore structure for efficient removal of Hg0 from flue gas. Journal of the Energy Institute. 2021, 98, 206-215.

[15]  Xiaopeng Zhang, Hang, Zhang, Xinxin Song, Xiangkai Han, Junjiang Bao, Ning Zhang, Gaohong He*. Co3O4-based catalysts derived from natural wood with hierarchical structure for elemental mercury oxidation. Journal of the Energy Institute. 2021, 94, 285-293.

[16]  Lili Huang, Zhiying Li, Yang Luo, Ning Zhang, Wenxu Qi, En Jiang, Junjiang Bao, Xiaopeng Zhang, Wenji Zheng, Baigang An*, Gaohong He*. Low-pressure loose GO composite membrane intercalated by CNT for effective dye/salt separation. Separation and Purification Technology. 2021, 256, 117839.

[17]  Ning Zhang, Wenxu Qi, Lili Huang, En Jiang, Zhiying Li, Yang Luo, Xiaopeng Zhang, Junjiang Bao, Wenji Zheng, Gaohong He*. A composite membrane of cross-linked GO network semi-interpenetrating in polysulfone substrate for dye removal from water. Journal of Membrane Science. 2020, 613, 118456.

[18]  En Jiang, Jun Huo, Yang Luo, Zhiying Li, Xiaopeng Zhang, Junjiang Bao, Gaohong He, Ning Zhang*. Influence of electric field on nanoconfined proton behaviours: A molecular dynamics simulation. Journal of Molecular Liquids. 2020, 319, 114113.

[19]  Junjiang Bao, Lei Zhang, Chunxiao Song, Ning Zhang, Xiaopeng Zhang, Gaohong He*. Comparative study of combined organic Rankine cycle and vapor compression cycle for refrigeration: Single fluid or dual fluid?. Sustainable Energy Technologies and Assessments. 2020, 37, 100595.

[20]  Hongda Zhu, Xinxin Song, Xiangkai Han, Xiaopeng Zhang*, Junjiang Bao, Ning Zhang, Gaohong He*. Co3O4 Nanosheets Preferentially Growing (220) Facet with a Large Amount of Surface Chemisorbed Oxygen for Efficient Oxidation of Elemental Mercury from Flue Gas. Environmental Science & Technology. 2020, 54, 14, 8601-8611.

[21]  Xiaopeng Zhang, Xiangkai Han, Chengfeng Li, Xinxin Song, Junjiang Bao, Ning Zhang, Gaohong He*, Promoting Effect of the Core-Shell Structure of MnO2@TiO2 Nanorods on SO2 Resistance in Hg0 Removal Process, Catalysts, 2020, 10 (1), 72-85.

[22]  Xiaopeng Zhang, Hang Zhang, Hongda Zhu, Chengfeng Li, Ning Zhang, Junjiang Bao*, Gaohong He*, Co3O4 Nanorods with a Great Amount of Oxygen Vacancies for Highly Efficient Hg0 Oxidation from Coal Combustion Flue Gas, Energy Fuels, 2019, 33, 6552−6561.

[23]  Xiaopeng Zhang, Bojian Tan, Jinxin Wang, Hang Zhang, Chengfeng Li and Gaohong He*, Removal of Elemental Mercury by Ce and Co Modified MCM-41 Catalyst from Simulated Flue Gas, The Canadian Journal of Chemical Engineering, 2019, 97, 734–742.

[24]  Junjiang Bao, Lei Zhang, Chunxiao Song, Ning Zhang, Minggang Guo, Xiaopeng Zhang*. Reduction of efficiency penalty for a natural gas combined cycle power plant with post-combustion CO2 capture: Integration of liquid natural gas cold energy. Energy Conversion and Management. 2019, 198, 111852.

[25]  Ning Zhang, Wenxu Qi, Lili Huang, En Jiang, Junjiang Bao, Xiaopeng Zhang, Baigang An*, Gaohong He*. Review on structural control and modification of graphene oxide-based membranes in water treatment: From separation performance to robust operation. Chinese Journal of Chemical Engineering. Chinese Journal of Chemical Engineering. 2019, 27, 1348-1360.

[26]  Junjiang Bao, Tong Yuan, Lei Zhang, Ning Zhang, Xiaopeng Zhang, Gaohong He*. Comparative study of liquefied natural gas (LNG) cold energy power generation systems in series and parallel. Energy Conversion and Management. 2019, 184, 107-126.

[27]  Ning Zhang, Boyun Yang, Jun Huo, Wenxu Qi, Xiaopeng Zhang, Xuehua Ruan, Junjiang Bao, Gaohong He*. Hydration structures of vanadium/oxovanadium cations in the presence of sulfuric acid: A molecular dynamics simulation study. Chemical Engineering Science. 2019, 195, 683-692.

[28]  Jun Huo, Wenxu Qi, Hongda Zhu, Boyun Yang, Gaohong He, Junjiang Bao, Xiaopeng Zhang, Xiaoming Yan, Li Gao, Ning Zhang *. Molecular dynamics simulation on the effect of water uptake on hydrogen bond network for OH? conduction in imidazolium-g-PPO membrane. International Journal of Hydrogen Energy. 2019, 44, 3760-3770.

[29]  Xiaopeng Zhang, Jinxin Wang, Bojian Tan, Ning Zhang, Junjiang Bao, Gaohong He *, Ce-Co interaction effects on the catalytic performance of uniform mesoporous Cex-Coy catalysts in Hg0 oxidation process, Fuel, 2018, 226, 15, 18-26.

[30]  Xiaopeng Zhang, Jinxin Wang, Zhuofeng Li, Yuezong Cui, Bojian Tan, Gaohong He*, Effects of Ni modification on NO-CO reaction with MnOx-CuO/TiO2 catalysts, The Canadian Journal of Chemical Engineering, 2018, 96, 1360-1366.

[31]  Yuechun Song, Jun Huo, Ning Zhang*, Junjiang Bao, Xiaopeng Zhang, Xuehua Ruan, Gaohong He*, Structural Characteristics of Hydrated Protons in Ion Conductive Channels: Synergistic Effect of the Sulfonate Group and Fluorine Studied by Molecular Dynamics Simulation, 2018, J. Phys. Chem. C, 122 (4), 1982–1989

[32]  Ning Zhang, Jun Huo, Boyun Yang, Xiaopeng Zhang, Junjiang Bao, Wenxu Qi, Gaohong He*, Understanding of imidazolium group hydration and polymer structure for hydroxide anion conduction in hydrated imidazolium-g-PPO membrane by molecular dynamics simulations. Chemical Engineering Science. 2018, 192, 1167-1176.

[33]  Junjiang Bao, Ruixiang Zhang, Yan Lin, Ning Zhang, Xiaopeng Zhang, Gaohong He*. The effect of the arrangements for compression process and expansion process on the performance of the two-stage condensation Rankine cycle, Energy Conversion and Management, 2018, 159, 299-311

[34]  Ning Zhang, Shaomin Chen, Boyun Yang, Jun Huo, Xiaopeng Zhang, Junjiang Bao, Xuehua Ruan, Gaohong He*, Effect of Hydrogen-Bonding Interaction on the Arrangement and Dynamics of Water Confined in a Polyamide Membrane: A Molecular Dynamics Simulation, J. Phys. Chem. B, 2018, 122, 17, 4719-4728

[35]  Junjiang Bao, Yan Lin, Ruixiang Zhang, Xiaopeng Zhang, Ning Zhang, Gaohong He*, Performance enhancement of two-stage condensation combined cycle for LNG cold energy recovery using zeotropic mixtures, Energy, 2018, 157, 588-598

[36]  Junjiang Bao, Ruixiang Zhang, Tong Yuan, Xiaopeng Zhang, Ning Zhang, Gaohong He*, A simultaneous approach to optimize the component and composition of zeotropic mixture for power generation systems, Energy Conversion and Management, 2018, 165, 354-362

[37]  Xiaopeng Zhang, Yuezong Cui, Jinxin Wang, Bojian Tan, Chengfeng Li, Hang Zhang, Gaohong He, Simultaneous removal of Hg0 and NO from flue gas by Co0.3-Ce0.35-Zr0.35O2 impregnated with MnOx, Chemical Engineering Journal, 2017, 326, 1210-1222

[38]  Xiaopeng Zhang, Zhuofeng Li, Jinxin Wang, Bojian Tan, Yuezong Cui, Gaohong He, Reaction mechanism for the influence of SO2 on Hg0 adsorption and oxidation with Ce0.1-Zr-MnO2, Fuel, 2017, 203, 308-315

[39]  Xiaopeng Zhang, Jinxin Wang, Bojian Tan, Zhuofeng Li, Yuezong Cui, Gaohong He, Ce-Co catalyst with high surface area and uniform mesoporous channels prepared by template method for Hg0 oxidation, Catalysis Communications, 2017, 98, 5-8

[40]  Xiaopeng Zhang, Zhuofeng Li, Jijun Zhao, Yuezong Cui, Bojian Tan, Jinxin Wang, Chengxiang Zhang, Gaohong He*, Mechanism of Ce promoting SO2 resistance of MnOx/γ-Al2O3: An experimental and DFT study, Korean Journal of Chemical Engineering, 2017, 34, 7, 2065-2071

[41]  Xiaopeng Zhang, Yuezong Cui, Bojian Tan, Jinxin Wang, Zhuofeng Li, Gaohong* He,  The adsorption and catalytic oxidation of element mercury over cobalt modified Ce-ZrO2 catalyst, RSC Advances, 2016, 6, 88332–88339

[42]  Xiaopeng Zhang, Yuezong Cui, Zhuofeng Li, Xuerong Zhou, He Gaohong*, Cobalt modification for improving K resistance of Mn/Ce-ZrO2 in selective catalytic reduction, Chemical Engineering & Technology, 2016, 39, 5, 874–882.

[43]  张呈祥, 张晓鹏*. Mn-Ce系列低温SCR催化剂抗硫性研究进展,化工进展, 2015, 34(7):1-7

[44]  周学荣, 张晓鹏*. SCR催化剂碱(土)金属中毒的研究进展,化学通报,2015, 7(78): 590-595.

[45]  Shen Boxiong*, Ma Hongqing, He Chuan, Zhang Xiaopeng, Low temperature NH3-SCR over Zr and Ce pillared clay based catalysts, Fuel Processing Technology, 119: 121-129, 2014

[46]  Zhang Xiaopeng, Shen Boxiong*, Wang Kai, Chen Jianhong, A contrastive study of the introduction of cobalt as a modifier for active components and supports of catalysts for NH3-SCR, Journal of Industrial and Engineering Chemistry, 19(4): 1272-1279, 2013

[47]  Zhang Xiaopeng, Shen Boxiong*, Chen Jianhong, Cai Ji, He Chuan, Wang Kai, Mn0.4/Co0.1Ce 0.45Zr0.45OX, a high performance catalyst for the selective catalytic reduction of NO by ammonia, Journal to the Energy Institute, 86(2): 119-124, 2013

[48]  Shen Boxiong*, Zhang Xiaopeng, Ma Hongqing, Yao Yan, Liu Ting, A comparative study of Mn/CeO2, Mn/ZrO2 and Mn/Ce-ZrO2 for low temperature selective catalytic reduction of NO with NH3 in the presence of SO2 and H2O, Journal of Environmental Sciences, 25(4): 791-800, 2013

[49]  Shen Boxiong*, Yao Yan, Chen Jianhong, Zhang Xiaopeng, Alkali metal deactivation of Mn–CeOx/Zr-delaminated-clay for the low-temperature selective catalytic reduction of NOx with NH3, Microporous and Mesoporous Materials, 180: 262-269, 2013

[50] 张晓鹏,沈伯雄*. 载体对Mn基催化剂低温NH3-SCR脱硝性能的影响,燃料化学学报,2013,411):123-128



授权专利:

1.   张晓鹏,程捷,王曦邈,王紫薇,贺高红,宋欣欣,用于脱汞的具有木材3D有序孔道结构的多孔Co3O4催化剂及其制备方法,ZL 2021 1 0264273.7

2.         张晓鹏;宋欣欣;贺高红,一种在木材碳上原位生长Co3O4纳米颗粒的催化剂及其制备方法,ZL 2020 1 0397044.8

3.         张晓鹏,朱宏达,贺高红,一种利用氧化石墨烯环氧基团锚定四氧化三钴制备催化剂的方法,ZL 2020 1 0397042.9

4.         张晓鹏,张航,贺高红,李成峰,一种用于脱汞的钴改性多孔生物炭催化剂的制备方法和应用,中国专利,ZL 2018 1 1598593.0,授权公告号,CN 109529845 B

  5.  张晓鹏,崔跃宗,贺高红,李卓峰,一种降低工业尿素中缩二脲含量的方法,中国专利,ZL 2015 1 0680489.6