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论文类型：期刊论文

发表时间：2014-01-01

发表刊物：JOURNAL OF MATERIALS CHEMISTRY A

收录刊物：SCIE、Scopus

卷号：2

期号：46

页面范围：19633-19640

ISSN号：2050-7488

摘要：3D hollow porous graphene balls (HPGBs) were synthesized directly from coal tar pitch for the first time by a simple nano-MgO template strategy coupled with KOH activation. The as-made HPGBs feature a 3D spherical architecture with a thin porous shell that has a high specific surface area and consists of macropores, mesopores and micropores in a well-balanced ratio. As the electrode material for supercapacitors, the as-made HPGBs show a high specific capacitance of 321 F g(-1) at 0.05 A g(-1), an excellent rate performance of 244 F g(-1) at 20 A g(-1), and good cycle stability with over 94.4% capacitance retention after 1000 cycles. This work may pave a new way for efficient and scaled-up production of low-cost spherical graphene materials, from aromatic hydrocarbon sources such as coal tar and heavy oils, for supercapacitors.