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Indexed by:期刊论文

Date of Publication:2017-10-01

Journal:SYNLETT

Included Journals:Scopus、SCIE

Volume:28

Issue:17

Page Number:2272-2276

ISSN No.:0936-5214

Key Words:aryl thiols; copper; sodium sulfide; 1,2-ethanedithiol; thiolation

Abstract:A copper-catalyzed direct and effective synthesis of aryl thiols from aryl iodides using readily available Na2S center dot 9H(2)O and 1,2-ethanedithiol was described. A variety of aryl thiols were readily obtained in yields of 76-99%. In this protocol, Na2S center dot 9H(2)O was used as ultimate sulfur source, and 1,2-ethanedithiol functioned as an indispensable catalytic reagent.