Release Time:2019-03-11  Hits:

Indexed by: Journal Article

Date of Publication: 2017-10-01

Journal: SYNLETT

Included Journals: SCIE、Scopus

Volume: 28

Issue: 17

Page Number: 2272-2276

ISSN: 0936-5214

Key Words: aryl thiols; copper; sodium sulfide; 1,2-ethanedithiol; thiolation

Abstract: A copper-catalyzed direct and effective synthesis of aryl thiols from aryl iodides using readily available Na2S center dot 9H(2)O and 1,2-ethanedithiol was described. A variety of aryl thiols were readily obtained in yields of 76-99%. In this protocol, Na2S center dot 9H(2)O was used as ultimate sulfur source, and 1,2-ethanedithiol functioned as an indispensable catalytic reagent.