Copper-Catalyzed Direct Synthesis of Aryl Thiols from Aryl Iodides Using Sodium Sulfide Aided by Catalytic 1,2-Ethanedithiol
点击次数：
论文类型：期刊论文
发表时间：2017-10-01
发表刊物：SYNLETT
收录刊物：SCIE、Scopus
卷号：28
期号：17
页面范围：2272-2276
ISSN号：0936-5214
关键字：aryl thiols; copper; sodium sulfide; 1,2-ethanedithiol; thiolation
摘要：A copper-catalyzed direct and effective synthesis of aryl thiols from aryl iodides using readily available Na2S center dot 9H(2)O and 1,2-ethanedithiol was described. A variety of aryl thiols were readily obtained in yields of 76-99%. In this protocol, Na2S center dot 9H(2)O was used as ultimate sulfur source, and 1,2-ethanedithiol functioned as an indispensable catalytic reagent.