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Heterologous perylene diimide arrays: potential non-fullerene acceptors in organic solar cells

Release Time:2019-03-11  Hits:

Indexed by: Journal Article

Date of Publication: 2017-09-14

Journal: JOURNAL OF MATERIALS CHEMISTRY C

Included Journals: EI、SCIE

Volume: 5

Issue: 34

Page Number: 8875-8882

ISSN: 2050-7526

Abstract: A new family of perylene diimide (PDI) arrays, heterologous ones (di-PDI and tri-PDI), were designed and efficiently synthesized by Suzuki cross-coupling reactions using two heterologous PDI monomers with different positions of bay- and ortho-substitution, respectively. The compounds exhibit unique photophysical and electrochemical properties and were successfully applied in non-fullerene organic solar cells with a superior power conversion efficiency of 4.55% for tri-PDI.

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