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Immobilization of ionic liquids to covalent organic frameworks for catalyzing the formylation of amines with CO2 and phenylsilane

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Indexed by:Journal Papers

Date of Publication:2016-01-01

Journal:CHEMICAL COMMUNICATIONS

Included Journals:SCIE

Volume:52

Issue:44

Page Number:7082-7085

ISSN No.:1359-7345

Abstract:We presented the immobilization of ionic liquids on the channel walls of COFs using a post-synthetic strategy. The ionic [Et4NBr](50%)-Py-COF afforded a high CO2 adsorption capacity of 164.6mg g(-1) (1 bar, 273 K) and was developed as an effective heterogeneous catalyst for the transformation of CO2 into value-added formamides under ambient conditions.

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