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个人信息Personal Information
副教授
博士生导师
硕士生导师
性别：女
毕业院校：大连理工大学
学位：博士
所在单位：化学学院
学科：无机化学
办公地点：大连理工大学西部校区化工综合楼
联系方式：0411
电子邮箱：jiaoyang@dlut.edu.cn
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M4L4 cerium cages assembled from ligands with lower symmetry as a molecular flask
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论文类型：期刊论文
发表时间：2014-01-01
发表刊物：INORGANIC CHEMISTRY COMMUNICATIONS
收录刊物：SCIE
卷号：39
页面范围：147-150
ISSN号：1387-7003
关键字：Cages; Molecular flask; Cyanosilylation
摘要：Cerium-based tetranuclear polyhedra Ce-YB1 and Ce-YB2 assembled from lower symmetrical ligands without three fold axle, can work as molecular flasks to catalyze cyanosilylation reactions of aldehyde molecules with suitable sizes. The size-selectively catalytic behavior of the cages was investigated by using large aldehydes as the substrate, based on which the corresponding cyanosilylation reactions could not be carried out on the same condition. (C) 2013 Published by Elsevier B.V.