Release Time:2019-03-13  Hits:

Indexed by: Journal Article

Date of Publication: 2016-02-01

Journal: FUNCTIONAL MATERIALS LETTERS

Included Journals: Scopus、EI、SCIE

Volume: 9

Issue: 1

ISSN: 1793-6047

Key Words: Metal-organic framework; trinuclear zinc cluster; pillar-layered framework; photoluminescent property

Abstract: A novel 3D metal-organic framework (MOF) {[Zn-3(bpdc)(3) (p-4-bpmb)](DMF)(2)}(n) (1) (H(2)bpdc = biphenyl-4,4'-dicarboxylic acid; p-4-bpmb = 1,4-bis(pyridine-4-ylmethoxy) benzene) has been solvothermally synthesized and structurally characterized. Compound 1 exhibits a 3D pillar-layered framework based on the trinuclear {Zn-3} building blocks, consisting of Zn-dicarboxylate layers and bipyridyl-derivative pillars. Furthermore, it features three-fold interpenetrating 8-connected hex-type topology. In addition, its thermal stability and luminescent property have also been investigated.