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DALIAN UNIVERSITY OF TECHNOLOGY Login 中文
Liu Ye

Researcher
Supervisor of Doctorate Candidates
Supervisor of Master's Candidates


Gender:Male
Alma Mater:大连理工大学
Degree:Doctoral Degree
School/Department:化工学院
Discipline:Applied Chemistry. Fine Chemicals. Polymer Chemistry and Physics
Business Address:Dalian University of Technology
F-207 West Campus, No.2 Linggong Road, High-Tech Zone, Dalian 116024, China
Contact Information:liuye@dlut.edu.cn
E-Mail:liuye@dlut.edu.cn
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Current position: Home >> Scientific Research >> Paper Publications

Asymmetric Copolymerization of CO2 with meso-Epoxides Mediated by Dinuclear Cobalt(III) Complexes: Unprecedented Enantioselectivity and Activity

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Indexed by:期刊论文

Date of Publication:2013-10-25

Journal:ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Included Journals:SCIE、EI、PubMed、Scopus

Volume:52

Issue:44

Page Number:11594-11598

ISSN No.:1433-7851

Key Words:carbon dioxide; cobalt; copolymerization; meso-epoxides; polycarbonates

Abstract:Unprecedented enantioselectivity and catalytic activity was observed in the asymmetric copolymerization of CO2 with meso-epoxides (including the less reactive cyclopentene oxide) mediated by the dinuclear Co(III) complex (S,S,S,S)-1 under mild conditions. The resultant copolymers possess more than 99 % carbonate linkages and a perfectly isotactic structure.Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

 

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