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论文类型：期刊论文

第一作者：Xu, Qin-Qin

通讯作者：Yin, JZ (reprint author), Dalian Univ Technol, Sch Chem Machinery, State Key Lab Fine Chem, Dalian 116024, Peoples R China.

合写作者：Ma, Yu-Ling,Xu, Gang,Ma, Jia-Xuan,Yin, Jian-Zhong,Wang, Ai-Qin,Gao, Jin-Ji

发表时间：2015-01-01

发表刊物：JOURNAL OF MATERIALS SCIENCE

收录刊物：SCIE、EI

卷号：50

期号：2

页面范围：855-862

ISSN号：0022-2461

摘要：Mesoporous KIT-6-supported highly dispersed silver nanoparticles and nano-networks were successfully synthesized in supercritical carbon dioxide and co-solvent solution using AgNO3 as a precursor, followed by calcinations. The nanocomposites were characterized by XRD, TEM, ICP, and N-2 adsorption-desorption isotherms. Three kinds of co-solvents were investigated including ethanol, the mixture of ethanol and ethylene glycol, and the mixture of ethanol and water. It was found that when only ethanol was used as a co-solvent, a small amount of AgNO3 was deposited onto the complex nanochannels of KIT-6 even if the deposition time was 12 h. However, it took a short deposition time of 1 h to deposit a large amount of precursors onto the substrates when the mixture of ethanol and ethylene glycol and the mixture of ethanol and water were used as co-solvents. The large solubility of AgNO3 in ethylene glycol or water had a positive effect on the dissolution of precursor in scCO(2), which was beneficial to the adsorption of precursor on the substrates.