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论文类型：期刊论文

第一作者：Yin, Jian-Zhong

通讯作者：Yin, JZ (reprint author), Dalian Univ Technol, Sch Chem Engn, Dalian 116012, Peoples R China.

合写作者：Xu, Qin-Qin,Wang, Ai-Qin

发表时间：2010-04-01

发表刊物：CHEMICAL ENGINEERING COMMUNICATIONS

收录刊物：SCIE、EI

卷号：197

期号：4

页面范围：627-632

ISSN号：0098-6445

关键字：Co-solvent; Copper; Nanocomposites; Nanorods; Supercritical fluid deposition

摘要：Copper nanoparticles and nanorods were prepared in the one-dimensional channels of SBA-15 supported by a modified supercritical fluid deposition (SCFD) method. In this approach, cheap and widely available copper nitrate, which is insoluble in supercritical CO2 (scCO2), was used as the copper source and ethanol as the co-solvent, thus avoiding the employment of expensive and less available scCO2-soluble precursors. The deposition was carried out at the pressure of 21-25MPa and temperature of 50 degrees C, followed by calcinations at 500 degrees C and H2 reduction at 500 degrees C. The results showed that highly dispersed Cu nanoparticles or nanorods were obtained controllably just by varying the deposition time, as characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD). On the other hand, when Cu(acac)2 was used as the precursor and without any co-solvent, only nanoparticles were formed in the channels of SBA-15 no matter how long the deposition time.