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论文类型：期刊论文
发表时间：2016-10-15
发表刊物：POLYHEDRON
收录刊物：SCIE、Scopus
卷号：117
页面范围：513-517
ISSN号：0277-5387
关键字：Indium(III); Tetracarboxylic acid; MOFs; Luminescence; Topology
摘要：Two unusual indium-organic frameworks, InMOF-1 and InMOF-2, have been successfully obtained by solvothermal reaction of trivalent indium ions and two flexible aromatic tetracarboxylate ligands. These compounds were characterized by single-crystal X-ray diffraction, IR spectroscopy, and powder X-ray diffraction (PXRD) measurement. In virtue of tetrahedral tri-positive and tetra-negative building blocks, their frameworks both exhibit anionic feature and are isomorphous in topology: twofold interpenetrating dia three-dimensional (3D) frameworks. Additionally, their solid-state photoluminescent properties have also been further investigated. (C) 2016 Elsevier Ltd. All rights reserved.