宋学志

个人信息Personal Information

副教授

博士生导师

硕士生导师

性别:男

毕业院校:中国科学院大学

学位:博士

所在单位:化工海洋与生命学院

办公地点:D03-302

联系方式:15604270228

电子邮箱:songxz@dlut.edu.cn

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Two novel anionic indium-tetracarboxylate frameworks: Syntheses, structures and photoluminescent properties

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论文类型:期刊论文

发表时间:2016-10-15

发表刊物:POLYHEDRON

收录刊物:SCIE、Scopus

卷号:117

页面范围:513-517

ISSN号:0277-5387

关键字:Indium(III); Tetracarboxylic acid; MOFs; Luminescence; Topology

摘要:Two unusual indium-organic frameworks, InMOF-1 and InMOF-2, have been successfully obtained by solvothermal reaction of trivalent indium ions and two flexible aromatic tetracarboxylate ligands. These compounds were characterized by single-crystal X-ray diffraction, IR spectroscopy, and powder X-ray diffraction (PXRD) measurement. In virtue of tetrahedral tri-positive and tetra-negative building blocks, their frameworks both exhibit anionic feature and are isomorphous in topology: twofold interpenetrating dia three-dimensional (3D) frameworks. Additionally, their solid-state photoluminescent properties have also been further investigated. (C) 2016 Elsevier Ltd. All rights reserved.