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个人信息Personal Information
教授
博士生导师
硕士生导师
主要任职：大连理工大学莱斯特国际学院副院长
性别：男
毕业院校：波鸿大学
学位：博士
所在单位：化工学院
学科：应用化学. 精细化工
办公地点：大连理工大学西部校区精细化工国家重点实验室E段521
联系方式：+86-411-84986487
电子邮箱：jinxuan.liu@dlut.edu.cn
Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity
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论文类型：期刊论文
发表时间：2017-01-01
发表刊物：RSC ADVANCES
收录刊物：SCIE、EI
卷号：7
期号：3
页面范围：1626-1633
ISSN号：2046-2069
摘要：Pd@MIL-101(Cr) hetero-catalysts have been successfully prepared using the metal-organic chemical vapour deposition (MOCVD) approach, by choosing [Pd(eta(3)-C3H5)(eta(5)-C5H5)] as a volatile precursor, and the hydrothermally stable metal-organic framework, MIL-101(Cr) as a support. The prepared Pd@MIL-101( Cr) hetero-catalysts characterized with various analytical techniques, exhibited highly monodispersed immobilized Pd nanoparticles in the MIL-101(Cr) cavities, while retaining the pristine crystallinity and porosity. The intact hybrid Pd@MIL-101(Cr) has been demonstrated to be an efficient catalyst for 2-butyne-1,4-diol hydrogenation with excellent activity, stability and selectivity (2-butene-1,4-diol (>94%)).