赵亮
senior experimentalist
Gender:Male
Alma Mater:大连理工大学
Degree:Doctoral Degree
School/Department:化工学院
Business Address:化学实验楼F406
Contact Information:zhaoliang716@dlut.edu.cn 0411-84986316
E-Mail:zhaoliang716@dlut.edu.cn
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Indexed by:期刊论文
Date of Publication:2017-02-01
Journal:INORGANIC CHEMISTRY COMMUNICATIONS
Included Journals:SCIE
Volume:76
Page Number:55-58
ISSN No.:1387-7003
Key Words:Anti ferromagnetic; Ferromagnetic; Polynuclear; Heterobimetallic system
Abstract:A tetranuclear cluster {[(Tp)Fe(CN)(3)]Co(pp)H2O}(2) . [(Tp)Fe(CN)(3)](2) .6H(2)O (1; Tp = hydrotris(pyrazoly)borate, pp = 2,6-bis(N-pyrazolyl)pyridine) and a hexanuclear cluster {[(pzTp)Fe(CN)(3)](2)Co(pp)}2.2H(2)O (2; pzTp = tetrakis(pyrazoly)borate) have been synthesized via rational assembly of the same (ppCo(II))(2+) unit and different tricyanometalate building blocks with varying proportions of sterically hindered groups. Magnetic measurements reveal that 1 exhibits the dominant antiferromagnetic interactions between Fe(III) and Co(II) ions, while 2 exhibits the dominant ferromagnetic interactions. (C) 2017 Elsevier B.V. All rights reserved.
2016年毕业于大连理工大学，获得理学博士学位。博士期间重要从事4d-5d过渡金属磁性功能配合物的合成和性能研究。2016年4月加入到大连理工大学精细化工国家重点实验室，负责多台大型仪器的管理和维护工作，并从事3d-5d过渡金属多功能分子磁性材料的合成与性能研究。
