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论文类型：期刊论文

发表时间：2019-05-10

发表刊物：ELECTROCHIMICA ACTA

收录刊物：SCIE、EI

卷号：305

页面范围：164-174

ISSN号：0013-4686

关键字：Ti3C2; Ni foam; Composite; Electrostatic self-assembly; Supercapacitor

摘要：The existence of the oxygen-containing functional groups on MXene surface makes it a potential electrode material in supercapacitor based on a redox mechanism. However, the irreversible stacking of MXenes will lead to an insufficient utilization of these functional groups. To solve this problem, we fabricated a composite electrode comprised of 2D delaminated Ti3C2 sheets (d-Ti3C2) and 3D Ni foam (NF) by electrostatic self-assembly. In this electrode, d-Ti3C2 nanosheets are adsorbed on the surface of 3D Ni foam skeleton structure, eliminating the need for insulative polymer binders. The self-assembly strategy endows d-Ti3C2/NF composites with unique 2D/3D structure which possesses the merits of excellent conductivity, sufficient active sites, high charge transfer efficiency and short ions diffusion path. As a result, the d-Ti3C2/NF composite electrode exhibits a high specific capacitance up to 654 F g(-1) at 1 A g(-1) and good cycling stability. An asymmetrical supercapacitor with d-Ti3C2/NF composite as a positive electrode, bulk Ti3C2 (b-Ti3C2) as a negative electrode and 6 M KOH as electrolyte, exhibits a maximum energy density of 18.1 Wh kg(-1) (at 397.8 W kg(-1)) and excellent cycling stability (80.6% after 5000 cycles). The results indicate that d-Ti3C2/NF composite is a promising electrode material for practical energy storage devices. (C) 2019 Elsevier Ltd. All rights reserved.